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811.
812.
We explore the contribution of fractures (joints) in controlling the rate of weathering advance for a low‐porosity rock by using methods of homogenization to create averaged weathering equations. The rate of advance of the weathering front can be expressed as the same rate observed in non‐fractured media (or in an individual block) divided by the volume fraction of non‐fractured blocks in the fractured parent material. In the model, the parent has fractures that are filled with a more porous material that contains only inert or completely weathered material. The low‐porosity rock weathers by reaction‐transport processes. As observed in field systems, the model shows that the weathering advance rate is greater for the fractured as compared to the analogous non‐fractured system because the volume fraction of blocks is < 1. The increase in advance rate is attributed both to the increase in weathered material that accompanies higher fracture density, and to the increase in exposure of surface of low‐porosity rock to reaction‐transport. For constant fracture aperture, the weathering advance rate increases when the fracture spacing decreases. Equations describing weathering advance rate are summarized in the ‘List of selected equations’. If erosion is imposed at a constant rate, the weathering systems with fracture‐bounded bedrock blocks attain a steady state. In the erosional transport‐limited regime, bedrock blocks no longer emerge at the air‐regolith boundary because they weather away. In the weathering‐limited (or kinetic) regime, blocks of various size become exhumed at the surface and the average size of these exposed blocks increases with the erosion rate. For convex hillslopes, the block size exposed at the surface increases downslope. This model can explain observations of exhumed rocks weathering in the Luquillo mountains of Puerto Rico. Published 2017. This article is a U.S. Government work and is in the public domain in the USA  相似文献   
813.
Molluscan shell debris is an under-exploited means of detecting, sourcing, and age-dating dredged sediments in open-shelf settings. Backscatter features on the Southern California shelf are suggestive of dredged sediment hauled from San Diego Bay but deposited significantly inshore of the EPA-designated ocean disposal site. We find that 36% of all identifiable bivalve shells > 2 mm (44% of shells > 4 mm) in sediment samples from this 'short dump' area are from species known to live exclusively in the Bay; such shells are absent at reference sites of comparable water depth, indicating that their presence in the short-dump area signals non-compliant disposal rather than natural offshore transport or sea level rise. These sediments lack the shells of species that invaded California bays in the 1970s, suggesting that disposal preceded federal regulations. This inexpensive, low-tech method, with its protocol for rejecting alternative hypotheses, will be easy to adapt in other settings.  相似文献   
814.
We present a model of chemical reaction within hills to explore how evolving porosity (and by inference, permeability) affects flow pathways and weathering. The model consists of hydrologic and reactive-transport equations that describe alteration of ferrous minerals and feldspar. These reactions were chosen because previous work emphasized that oxygen- and acid-driven weathering affects porosity differently in felsic and mafic rocks. A parameter controlling the order of the fronts is presented. In the absence of erosion, the two reaction fronts move at different velocities and the relative depths depend on geochemical conditions and starting composition. In turn, the fronts and associated changes in porosity drastically affect both the vertical and lateral velocities of water flow. For these cases, estimates of weathering advance rates based on simple models that posit unidirectional constant-velocity advection do not apply. In the model hills, weathering advance rates diminish with time as the Darcy velocities decrease with depth. The system can thus attain a dynamical steady state at any erosion rate where the regolith thickness is constant in time and velocities of both fronts become equal to one another and to the erosion rate. The slower the advection velocities in a system, the faster it attains a steady state. For example, a massive rock with relatively fast-dissolving minerals such as diabase – where solute transport across the reaction front mainly occurs by diffusion – can reach a steady state more quickly than granitoid rocks in which advection contributes to solute transport. The attainment of a steady state is controlled by coupling between weathering and hydrologic processes that force water to flow horizontally above reaction fronts where permeability changes rapidly with depth and acts as a partial barrier to fluid flow. Published 2020. This article is a U.S. Government work and is in the public domain in the USA.  相似文献   
815.
As part of a study on microbial redox alteration of humic substances we investigated the potential effect of this metabolism on the fate of heavy metals and hydrocarbons as a result of conformational alteration of the humic molecular structure due to microbial reduction. Our studies indicate that the microbial reduction of humic acids (HA) results in significant morphological and geochemical alterations. X‐ray microscopy analysis indicate that the conformational structure of the humic colloids is altered as a result of the redox change. In the reduced state, the HA appeared as small dense particles, on reoxidation, large loose aggregates were formed. In addition, spectrofluorometric studies indicated that the binding capacity of the HA for naphthalene was decreased by 10% when the HA was reduced. Similarly, the reduced HA yielded higher surface tension values at all concentrations tested which is indicative of a more hydrophilic and less hydrophobic solute. On reoxidation, the surface tension values reverted back to values similar to those obtained for the untreated oxidized HA. These data indicate that the hydrophobicity of the HA is altered on biological reduction of the HA and that this alteration is reversible. In contrast the reduced HA demonstrated a 15% higher affinity for heavy metals such as divalent cobalt than the oxidized HA. In addition to increasing the binding capacity of HA for heavy metals, the reduction of the HA also decreased the bioavailability and toxicity of bound heavy metals such as chromium. When incubated in the presence of Cr(III) and HA, cells of Escherichia coli grew much more rapidly in the presence of the reduced HA suggesting that the higher metal binding capacity of the reduced humic substances resulted in a removal of the Cr(III) from solution and hence reduced its bioavailability and toxicity. These studies demonstrate that HA redox state and reduction of humic acids by microorganisms can have a significant effect on the molecular morphology and binding constants of HA for heavy metals and hydrocarbons and also directly affects the bioavailability of these compounds in the environment.  相似文献   
816.
817.
Resin‐impregnated sediment blocks are a by‐product of micromorphological sample processing. These blocks can be further studied using a variety of destructive, nondestructive, and minimally destructive geochemical techniques. X‐ray fluorescence microanalyses conducted on sediment blocks yield semiquantitative major and trace elemental abundances that can be used to generate compositional maps, and to illustrate compositional change within or between archaeological strata and features. Sediment blocks can also be drilled to obtain small sediment samples for stable oxygen and carbon isotopic analyses. Both elemental and isotopic analyses can be conducted in conjunction with micromorphological analyses to yield a holistic picture of archaeological sediment composition, source, and depositional processes. The integration of micromorphological, compositional, and isotopic analyses is used here to aid in the differentiation of calcareous ash and lime plasters from the Neolithic site of Asıklı Höyük, Turkey.  相似文献   
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